V. I. Krinichnyi, A. E. Pelekh, L. I. Tkachenko, G. I. Kozub, Study of spin dynamics in trans-polyacetylene at 2-mm waveband EPR, Synth. Met., 46 (1992) 1.
Abstract. Electron spin-lattice, T1, and spin-spin, T2, relaxation times in polyacetylene samples have been measured by a saturation method at 2-mm waveband EPR at 90-330 K. Temperature dependences of the intrachain diffusion and interchain hopping rates in trans-(CH)x are evaluated. Spin dynamics in pristine trans-(CH)x does not agree with the predictions of the soliton model, but it is in a good agreement with the intersoliton isoenergetic electron hopping model of charge transport predicted by Kivelson.